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Extend the life of your Li-Ion Battery By Adam Nash

Li-Ion Batteries

There are 2 problems with lithium ion batteries; they can explode if abused, and they will become useless fairly quickly if treated badly. Happily, it's pretty hard to explode a li-ion battery (the most common cause is penetration; so keep your spare batteries in a tough, rigid container!), but there are some basic things you should do to minimise the risk. Only buy protected batteries; that is, batteries with a protection PCB. This limits the max. discharge current (about 7A, so you won't notice this limit until you short the battery), and prevents over-charge and over-discharge. Take the batteries off the charger as soon as you can after they've finished charging; overcharging is the most common way to damage a cell, or even cause it to explode. Don't leave batteries badly discharged for long periods of time; if your light shuts off because of the protection circuit, then recharge the battery within a maximum of twenty four hours; leaving it longer rapidly ages the cell, lowering its capacity and making it more likely to vent with flame. And (I hope this one is obvious!), don't short circuit the battery.
images/food_container_battery_fits
A tough waterproof container protects your spares

Don't be Dim!
For day to day use, they shouldn't be discharged beyond 80%, which correlates to an open circuit voltage of about 3.7V, which is reached just after the point of noticeable dimming on full power with the average P7/single 18650 light (In my sample, 3.74V was the point of dimming). If you want decent cycle life, don't discharge beyond this level and swap batteries as soon as you notice dimming; bouncing off the protection circuit as your limit for discharge is definitely a bad idea. When you've just got in from a cold ride, let the cells sit in a room to warm up a bit before you charge them; charging a cell with a core temperature below 00C causes damage, though they can be discharged safely at -200C with only slightly less capacity than a discharge at +200C. Keeping cells in a hot car isn't too bad for short periods of time, but long term won't help them at all.

Keep your cool
When storing cells over the summer, discharge to about 40% (reached after ~40 minutes on full blast with a P7 light), or 3.9V (open circuit voltage), and try to keep them somewhere cool, such as a basement, or wine cellar if you're posh. Keeping the cells at 100% charge in warm conditions is very bad for them, and they'll be near useless next year.

You can tell if a cell is getting worn out by checking how well it holds charge over about a week; if you fully charge it to 4.2V, then a week later it reads 4.1V, then it's on its way out. If it reads 4.0V within a week, then you've damaged the cell, and the risk of explosion is far greater; I'd strongly advise you replace the cell(s) in question if they reach this level. At £3 each, the risk of having it explode while helmet mounted really isn't worth it.

Li-Ion_Charger_Dedicated
Dedicated charger: the safe way to charge cells

Super safe cells:
If you're really worried about exploding cells, you can consider IMR18650's They have less capacity, so expect 30 to 40 minutes runtime. They have no protection circuit, so it's especially important that you don't overdischarge or short circuit them. Their advantages are a much higher max charge/discharge rate and higher cycle life, and they won't vent with flame no matter what you do. Apart from that, they can be treated much as "normal" li-ion batteries.

With thanks to the following excellent sources of battery information:

Battery University

Candlepower Forums

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